synthesis and characterization of zno nanoparticles pdf

Synthesis And Characterization Of Zno Nanoparticles Pdf

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The present study reports the synthesis of ZnO-NPs using Acantholimon serotinum extracts followed by characterization and evaluation of biological activities.

Zinc oxide nanoparticles were synthesized using a simple precipitation method with zinc sulfate and sodium hydroxide as starting materials. The synthesized sample was calcined at different temperatures for 2 h. SEM images show various morphological changes of ZnO obtained by the above method. The average crystallite sizes of the samples were calculated from the full width at half maximum of XRD peaks by using Debye-Scherrer's formula and were found to be in the nanorange.

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Government Kalasala, Jangareddygudem , India. ZnO nanoparticles have been synthesized by precipitation method from Zinc nitrate. The powder was characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, selected-area electron diffraction, UV-vis optical absorption, and photoluminescence spectroscopy analyses.

XRD patterns showed that ZnO nanoparticles have hexagonal unit cell structure. The synthesis method has potential for application in manufacturing units due to ease processing and more economical reagents. Nowadays, there has been an increasing demand for the development of nanosized semiconductors due to their significant electrical and optical properties which are highly useful in fabricating nanoscaled optoelectronic and electronic devices with multifunctionality [ 1 — 3 ].

Among various semiconducting materials, zinc oxide ZnO is a distinctive electronic and photonic wurtzite n-type semiconductor with a wide direct band gap of 3. The high exciton binding energy of ZnO would allow for excitonic transitions even at room temperature, which could mean high radiative recombination efficiency for spontaneous emission as well as a lower threshold voltage for laser emission.

The lack of a centre of symmetry in wurtzite, combined with a large electromechanical coupling, results in strong piezoelectric and pyroelectric properties and hence the use of ZnO in mechanical actuators and piezoelectric sensors [ 6 , 7 ]. ZnO is potential candidate for optoelectronic applications in the short wavelength range green, blue, UV , information storage, and sensors as it exhibits similar properties to GaN [ 8 — 10 ].

ZnO nanoparticles are promising candidates for various applications, such as nanogenerators [ 11 ], gas sensors [ 12 ], biosensors [ 13 ], solar cells [ 14 ], varistors [ 15 ], photodetectors [ 16 ], and photocatalysts [ 17 ]. From the literature survey, it was found that various approaches for the preparation of ZnO nanopowders have been developed, namely, sol-gel, microemulsion, thermal decomposition of organic precursor, spray pyrolysis, electrodeposition, ultrasonic, microwave-assisted techniques, chemical vapor deposition, and hydrothermal and precipitation methods [ 18 — 27 ].

Most of these techniques were not extensively used on a large scale, but chemical synthesis has been widely used due to its simplicity and less expensive. In the present study, we report the synthesis of ZnO nanoparticles using chemical method and the characterization of ZnO nanoparticles using X-ray diffraction, scanning electron microscopy SEM , transmission electron microscopy TEM , selected area electron diffraction SAED , UV-vis absorbance, and photoluminescence spectra is discussed.

Zinc nitrate, sodium hydroxide, and ethanol were purchased and used without further purification. Zinc oxide nanoparticles were synthesized by wet chemical method using zinc nitrate and sodium hydroxide precursors. In this experiment, a 0. After complete dissolution of zinc nitrate, 0.

After the completion of reaction, the solution was allowed to settle for overnight and further, the supernatant solution was separated carefully.

The prepared ZnO nanoparticles were characterized for their optical and nanostructural properties. Morphology of the sample was investigated using scanning electron microscope SEM with EDXA, Sirion which also has been used for compositional analysis of the prepared ZnO nanoparticles.

As part of our research programme, we synthesize nanoparticles with enhanced particle properties using chemical routes that help in controlling the surface energy. The functionalized particles were characterized by the following techniques. Figure 1 represents the X-ray diffraction pattern of ZnO nanopowder. A definite line broadening of the XRD peaks indicates that the prepared material consist of particles in nanoscale range. The diffraction peaks located at The average particle size of the sample was found to be These pictures confirm the formation of ZnO nanoparticles.

These pictures substantiate the approximate spherical shape to the nanoparticles, and most of the particles exhibit some faceting. The selected area electron diffraction SAED pattern Figure 3 shows distinct bright rings which confirm the preferential orientation of nanocrystals instead of irregular [ 29 , 32 ].

Transmission electron microscopic pictures Figures 4 a , 4 b , and 4 c have also revealed the ZnO nanoparticles formation produced at different magnifications by confirming the hexagonal plane to the prepared nanoparticles. The size of the nanoparticles plays an important role in changing the entire properties of materials.

Thus, size evolution of semiconducting nanoparticles becomes very essential to explore the properties of the materials. UV-visible absorption spectroscopy is widely being used technique to examine the optical properties of nanosized particles. The absorption spectrum of ZnO nanopowder is shown in Figure 4. It is also evident that significant sharp absorption of ZnO indicates the monodispersed nature of the nanoparticle distribution [ 8 ].

This result has also been confirmed by the SEM pictures. The photoluminescence originates from the recombination of surface states.

The strong PL implies that the surface states remain very shallow, as it is reported that quantum yields of band edge will decrease exponentially with increasing depth of surface state energy levels [ 38 , 39 ]. The emission is caused by the radiative recombination of a photogenerated hole with an electron occupying the oxygen vacancy [ 28 , 40 ].

Further, the spectrum also reveals the narrow size distribution of nanoparticles in the powder as the luminescence peak full-width half-maximum FWHM is only in few nanometers [ 42 ]. SAED pattern consists of bright uniform rings confirming preferential orientation for nanocrystals instead of random orientation.

From UV-vis absorption spectrum, the calculated average size of the prepared ZnO nanoparticles is found to be 2. These ZnO nanoparticles can be used in different industrial applications, namely, luminescent material for fluorescent tubes, active medium for lasers, sensors, and so forth.

The authors would like to thank the management and the director of Lakireddy Bali Reddy College of Engineering for their constant encouragement and financial support to carry out this work. This is an open access article distributed under the Creative Commons Attribution License , which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Academic Editor: Z. Crnjak Orel. Received 01 Feb Accepted 04 Mar Published 22 May Abstract ZnO nanoparticles have been synthesized by precipitation method from Zinc nitrate. Introduction Nowadays, there has been an increasing demand for the development of nanosized semiconductors due to their significant electrical and optical properties which are highly useful in fabricating nanoscaled optoelectronic and electronic devices with multifunctionality [ 1 — 3 ]. Experimental Methods Zinc nitrate, sodium hydroxide, and ethanol were purchased and used without further purification.

Results and Discussion As part of our research programme, we synthesize nanoparticles with enhanced particle properties using chemical routes that help in controlling the surface energy. Figure 1. Figure 2. SEM pictures of ZnO nanoparticles at different magnifications. Figure 3. Figure 4. High-resolution transmission electron microscopic pictures of ZnO nanoparticles. Figure 5. UV-vis absorption spectrum of ZnO nanoparticles.

Figure 6. References M. Tokumoto, V. Briois, C. Santilli, and S. Kumar, L. Panchakarla, S. Bhat, U. Maitra, K. Subrahmanyam, and C. Rao and A. Govindaraj, in Nanotubes and Nanowires , H. Kroto, P. Craighead, Eds. Ko, Y. Kim, S. Lee, S. Choi, and S. Zaouk, Y. Zaatar, R. Asmar, and J. Zhang, Z. Xue, and Q. Hayashi, A. Ishizaka, M. Haemori, and H. Ng, B. Chen, J. Li et al. Gao, Y. Ding, W. Mai, W. Hughes, C. Lao, and Z. Cheng, H. Zhao, L.

SYNTHESIS AND CHARACTERIZATION OF ZnO NANO-PARTICLES

These metrics are regularly updated to reflect usage leading up to the last few days. Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric. Find more information on the Altmetric Attention Score and how the score is calculated. The potential ecotoxicity of nanosized zinc oxide ZnO , synthesized by the polyol process, was investigated using common Anabaena flos-aquae cyanobacteria and Euglena gracilis euglenoid microalgae.

Thank you for visiting nature. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser or turn off compatibility mode in Internet Explorer. In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript. Compared with the individually dispersed ZnO nanoparticles, the as-prepared HNTs ZnO nanocomposites showed a smaller band gap energy and relatively strong light absorption. With the development and progress of society, the importance and value of natural nanomaterials in science has been acknowledged. These nanomaterials have the potential to be used as inexpensive alternatives to expensive carbon nanotubes or other nanomaterials for various applications 5 , 6.


Narrow band gap zinc oxide (ZnO) nanoparticles (NPs) were synthesized using unboiled and boiled leaf extracts of Costus woodsonii. The as-.


Synthesis, Characterization, and Spectroscopic Properties of ZnO Nanoparticles

Cynara scolymus leaves were used in the green synthesis of zinc oxide nanoparticles ZnO NPs. ZnO NPs was confirmed by the formation of a white precipitate. The use of SEM confirmed the spherical shape of the nanoparticles, which had an average size of The nanoparticle zinc

This study consists of a reliable process for synthesizing ZnO NPs by green method. Here, Eucalyptus globulus Labill. The band-gap of the ZnO were measured to be around 2.

In this work, nanoparticles of zinc oxide ZnO-NPs were synthesized using acetic acid, ethanol and ethylene glycol as solvents. To determine the physicochemical and structural characteristics of the synthesized nanoparticles, IR spectroscopy, X-ray diffraction, UV—Vis spectroscopy and transmission electron microscopy were used. The band gap of ZnO-Nps depends of synthesis solvent used: 3. Based on the information from the characterization of the ZnO-NPs synthesized, the spheroidal nanoparticles were selected, to determine their antifungal capacity on cultures of Aspergillus niger strains. This is a preview of subscription content, access via your institution.

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2 Comments

  1. Dorian L.

    Government Kalasala, Jangareddygudem , India.

    27.11.2020 at 07:00 Reply
  2. Lothair D.

    Skip to search form Skip to main content You are currently offline.

    29.11.2020 at 10:28 Reply

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